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279811

Sigma-Aldrich

Bis(cyclopentadienyl)cobalt(III) hexafluorophosphate

98%

Synonym(s):

Cobaltocenium hexafluorophosphate

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About This Item

Empirical Formula (Hill Notation):
C10H10CoF6P
CAS Number:
12427-42-8
Molecular Weight:
334.08
EC Number:
235-655-3
MDL number:
MFCD00011874
UNSPSC Code:
12161600
PubChem Substance ID:
24856910
NACRES:
NA.22

$63.85

List Price$69.40Save 8%
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Available to ship onMay 02, 2025Details

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Quality Level

100

assay

98%

reaction suitability

core: cobalt
reagent type: catalyst

SMILES string

[Co+].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2.F[P-](F)(F)(F)(F)F

InChI

1S/2C5H5.Co.F6P/c2*1-2-4-5-3-1;;1-7(2,3,4,5)6/h2*1-5H;;/q;;+1;-1

Inchi Key

IASMSXQWVNBFOM-UHFFFAOYSA-N

Application

Uses:
  • Cocatalyst for Heck reaction of aryl iodides with alkenes using palladium as catalyst in water
  • Reactant for modification of organometallic electrodes surfaces through cathodic reduction
  • Reactant in synthesis and solution self-assembly of side-chain cobaltocenium-containing block copolymers

Pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCV5065
MKCS6673
MKCQ9270
MKCM4992
MKCK0176

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Javiera Cáceres et al.
Physical chemistry chemical physics : PCCP, 19(3), 2574-2582 (2017-01-07)
Biosupramolecular assemblies combining cucurbit[n]urils (CB[n]s) and proteins for the targeted delivery of drugs have the potential to improve the photoactivity of photosensitizers used in the photodynamic therapy of cancer. Understanding the complexity of these systems and how it affects the

Questions

  1. What is the solubility?

    1 answer

    1. This product is not tested for solubility. However, various sources note that this compound is soluble in dry acetone, dimethylformamide, and hot ethanol. No rate has been reported.

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