245267

Manganese(0) carbonyl

98%

• Synonym(s): Decacarbonyl dimanganese(0), Dimanganese(0) decacarbonyl
• Linear Formula: Mn₂(CO)₁₀
• CAS Number: 10170-69-1
• Molecular Weight: 389.98
• EC Number: 233-445-6
• MDL number: MFCD00011115
• UNSPSC Code: 12352103
• PubChem Substance ID: 24854511
• NACRES: NA.23

Properties

• assay: 98%
• form: powder or crystals
• reaction suitability: core: manganese; reagent type: catalyst
• mp: 154 °C (lit.)
• storage temp.: 2-8°C
• SMILES string: [Mn].[Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
• InChI: 1S/10CO.2Mn/c10*1-2;;
• InChI key: QFEOTYVTTQCYAZ-UHFFFAOYSA-N

Description

General description

Manganese(0) carbonyl, also known as Decacarbonyl dimanganese exhibits interesting electrochemicalproperties owing to the presence of carbonyl ligands and the manganese metalcenters. In electrochemistry, this compound can act as a carbonyl source andpotentially participate in redox reactions.

Application

Manganese(0) carbonyl can be used:

• As a precursor to prepare Ni₂–xMnxP nanoparticles to fabricate a catalyst for electrochemical oxygen evolution reaction(OER).
• To fabricate an ultra-sensitive manganese doped MoS₂ electrochemical dopamine sensor via modified chemical vapor deposition(CVD) method.
• As a reducing agent to synthesize Pt-Co electrocatalyst for oxygen reduction reactions in fuel cells. Mn and CO atoms produced during decomposition acts as reducing and surface structure guiding agents respectively.

Safety Information

• pictograms: GHS06
• signalword: Danger
• hcodes: H331
• pcodes: P261 - P271 - P304 + P340 + P311 - P403 + P233 - P405 - P501
• Hazard Classifications: Acute Tox. 3 Inhalation
• Storage Class: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges