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180025

Sigma-Aldrich

3-Bromoaniline

98%

Synonym(s):

(3-Bromophenyl)amine, (m-Bromophenyl)amine, 1-Amino-3-bromobenzene, 3-Amino-1-bromobenzene, 3-Bromobenzenamine, m-Aminobromobenzene, m-Bromoaniline

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About This Item

Linear Formula:
BrC6H4NH2
CAS Number:
591-19-5
Molecular Weight:
172.02
Beilstein/REAXYS Number:
742028
EC Number:
209-704-4
MDL number:
MFCD00007757
UNSPSC Code:
12352100
PubChem Substance ID:
24850844
NACRES:
NA.22

assay

98%

form

liquid

refractive index

n20/D 1.625 (lit.)

bp

251 °C (lit.)

mp

15-18 °C (lit.)

density

1.58 g/mL at 25 °C (lit.)

SMILES string

Nc1cccc(Br)c1

InChI

1S/C6H6BrN/c7-5-2-1-3-6(8)4-5/h1-4H,8H2

InChI key

DHYHYLGCQVVLOQ-UHFFFAOYSA-N

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General description

The in vitro nephrotoxic potential of 3-bromoaniline was studied.

Application

3-Bromoaniline was used in the synthesis of amino substituted quinazoline.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

>446.0 °F

flash_point_c

> 230 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

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Cobb JM, et al.
Tetrahedron Letters, 40(5), 1045-1048 (1999)
Xiao-Feng Wu et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(40), 12599-12602 (2012-09-05)
(C), its (O)K! An efficient palladium-catalyzed carbonylative synthesis of 2-alkylbenzoxazinones has been developed. By starting from 2-bromoanilines and acid anhydrides, the corresponding products were isolated in good yields.
G O Rankin et al.
Journal of applied toxicology : JAT, 15(2), 139-146 (1995-03-01)
Haloanilines are commonly used as chemical intermediates in the manufacture of a wide range of products. The purpose of this study was to examine the in vivo nephrotoxic and hepatotoxic potentials of the 3-haloanilines. The in vitro effects of the
L A Khawli et al.
International journal of radiation applications and instrumentation. Part B, Nuclear medicine and biology, 19(3), 297-301 (1992-04-01)
Biotinyl-m-[125I]iodoanilide (BIA) was synthesized by coupling biotin to m-[125I]iodoaniline via a mixed anhydride reaction. m-[125I]Iodoaniline was produced from the tin precursor, which was prepared using a palladium catalyzed reaction of hexabutylditin with m-bromoaniline. The radioiodinated BIA derivative is characterized by
Ali Sarafraz Yazdi et al.
Journal of chromatography. A, 1082(2), 136-142 (2005-07-23)
A novel method for the extraction of aromatic amines present in water samples is produced here coupling two-step liquid-phase microextraction with high performance liquid chromatography by using a monolithic column. The hydrophobic porous polypropylene membranes were used as the interface

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