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148938

Sigma-Aldrich

2-Iodopropane

contains copper as stabilizer, 99%

Synonym(s):

Isopropyl iodide

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About This Item

Linear Formula:
(CH3)2CHI
CAS Number:
75-30-9
Molecular Weight:
169.99
Beilstein:
1098244
EC Number:
200-859-3
MDL number:
MFCD00001071
UNSPSC Code:
12352100
PubChem Substance ID:
24848923
NACRES:
NA.22

Quality Level

200

Assay

99%

form

liquid

contains

copper as stabilizer

refractive index

n20/D 1.498 (lit.)

bp

88-90 °C (lit.)

mp

−90 °C (lit.)

density

1.703 g/mL at 25 °C (lit.)

SMILES string

CC(C)I

InChI

1S/C3H7I/c1-3(2)4/h3H,1-2H3

InChI key

FMKOJHQHASLBPH-UHFFFAOYSA-N

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General description

2-Iodopropane is an organ iodine compound. It is commonly used as a homolytic and heterolytic alkylating agent and in the preparation of the α-isopropoxymethylene blocking group. Additionally, it acts as an intermediator in the conversion of thiocarbonate to alkene.

Application

2-Iodopropane (Isopropyl iodide) was used to prepare butyric and isobutyric acid.

2-Iodopropane is used as an alkylating agent in the conversion of phenols, alcohols, oximes, carboxylic acids, and heteroatomic compounds (indoles, pyridines, purines, tetrazoles, pyrazoles, and amines) to give corresponding products.

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Warning

Hazard Statements

H226,H302,H315,H319

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

107.6 °F - closed cup

Flash Point(C)

42 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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2-Iodopropane
Wilson PD and Hilmey DG
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2001)
Timur Coskun et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(21), 6840-6844 (2013-03-29)
Glycerol is converted to a mixture of butyric and isobutyric acid by rhodium- or iridium-catalysed carbonylation using HI as the co-catalyst. The initial reaction of glycerol with HI results in several intermediates that lead to isopropyl iodide, which upon carbonylation
Joe Rashan et al.
Journal of AOAC International, 86(4), 694-702 (2003-09-26)
An alternative liquid chromatographic (LC) method was developed and validated for the simultaneous determination of methoxyl and 2-hydroxypropoxyl substituents in hypromellose and hypromellose acetate succinate. The method uses the hydriodic acid cleavage reaction, catalyzed by adipic acid, of the substituted
Shanshan Zhang et al.
Analytica chimica acta, 978, 24-34 (2017-06-10)
Stable isotope chemical labeling liquid chromatography-mass spectrometry (LC-MS) is a powerful strategy for comprehensive metabolomics profiling, which can improve metabolites coverage and quantitative information for exploration of metabolic regulation in complex biological systems. In the current work, a novel stable
W Kenealy et al.
Journal of bacteriology, 146(1), 133-140 (1981-04-01)
Iodopropane inhibited cell growth and methane production when Methanobacterium thermoautotrophicum, Methanobacterium formicicum, and Methanosarcina barkeri were cultured on H2-CO2. Iodopropane (40 microM) inhibited methanogenesis (30%) and growth (80%) when M. barkeri was cultured mixotrophically on H2-CO2-methanol. The addition of acetate
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