515892

Calcium trifluoromethanesulfonate

99.9%

• Sinónimos: Calcium triflate
• Fórmula lineal: (CF₃SO₃)₂Ca
• Número de CAS: 55120-75-7
• Peso molecular: 338.22
• Número MDL: MFCD00143911
• Código UNSPSC: 12352302
• ID de la sustancia en PubChem: 24873852
• NACRES: NA.22

Propiedades

• grado: for analytical purposes
• Nivel de calidad: 200
• Ensayo: 99.9%
• mp: 350 °C (lit.)
• grupo funcional: fluoro; triflate
• cadena SMILES: [Ca++].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F
• InChI: 1S/2CHF3O3S.Ca/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2
• Clave InChI: PUQLFUHLKNBKQQ-UHFFFAOYSA-L

Descripción

Descripción general

Calcium trifluoromethanesulfonate, also known as calcium triflate [Ca(OTf)₂], is widely employed as a Lewis acid catalyst in organic synthesis. It facilitates a range of reactions, including the aldol reaction, Michael additions, and ring-opening reactions of epoxides. In addition, it is also used as a reagent for the preparation of trifluoromethanesulfonate esters, which can be used as leaving groups in a range of organic transformations.

Aplicación

Calcium trifluoromethanesulfonate can be used as a catalyst to synthesize β-amino alcohols via aminolysis of epoxides. It is also used in the one-pot conversion of aldehydes to their corresponding nitrile compounds.

Información de seguridad

• Pictogramas: GHS07
• Palabra de señalización: Warning
• Frases de peligro: H315,H319
• Consejos de prudencia: P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313
• Clasificaciones de peligro: Eye Irrit. 2 - Skin Irrit. 2
• Código de clase de almacenamiento: 13 - Non Combustible Solids
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): Not applicable
• Punto de inflamabilidad (°C): Not applicable
• Equipo de protección personal: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges