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Merck

433063

Sigma-Aldrich

Sodium methanesulfinate

technical grade, 85%

Sinónimos:

Methanesulfinic acid sodium salt

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About This Item

Fórmula lineal:
CH3SO2Na
Número de CAS:
Peso molecular:
102.09
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

grade

technical grade

Quality Level

assay

85%

mp

222-226 °C (dec.) (lit.)

functional group

sulfinic acid

SMILES string

[Na+].CS([O-])=O

InChI

1S/CH4O2S.Na/c1-4(2)3;/h1H3,(H,2,3);/q;+1/p-1

InChI key

LYPGDCWPTHTUDO-UHFFFAOYSA-M

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General description

Sodium methanesulfinate is an aliphatic sodium sulfinate. Conjugate addition of sodium methanesulfinate to vinyl heterocycles has been described. Cross-coupling reaction between aryl boronic acid and sodium methanesulfinate has been studied. Its stock solution was prepared from methanesulfonic acid by adding one equivalent of sodium hydroxide and diluting it to 4M.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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R Bruck et al.
Journal of hepatology, 35(4), 457-464 (2001-10-30)
Reactive oxygen species and oxidative stress were implicated in hepatic stellate cell activation and liver fibrosis. The aim of the present study was to examine whether the administration of free radical scavengers in vivo would prevent experimentally-induced hepatic cirrhosis in
Design, Synthesis and Discovery of 1-(2-(6-Chloro-3-methylsulfonyl)-naphthyl)-1H-pyrazole-5-carboxylamides as Highly Potent Factor Xa Inhibitors.
Jia ZJ, et al.
Chemical & Pharmaceutical Bulletin, 57(9), 1004-1007 (2009)
A mild and efficient new synthesis of aryl sulfones from boronic acids and sulfinic acid salts.
Beaulieu C, et al.
Tetrahedron Letters, 45(16), 3233-3236 (2004)
Matthew L Dawson et al.
Proceedings of the National Academy of Sciences of the United States of America, 109(46), 18719-18724 (2012-10-24)
Airborne particles affect human health and significantly influence visibility and climate. A major fraction of these particles result from the reactions of gaseous precursors to generate low-volatility products such as sulfuric acid and high-molecular weight organics that nucleate to form
Conjugate addition of sodium methanesulfinate to vinyl pyridines and diazines for the synthesis of aliphatic sulfones.
Schaaf GM, et al.
Tetrahedron Letters, 50(17), 1928-1933 (2009)

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