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342041

Sigma-Aldrich

Perfluoroheptanoic acid

≥97.0%

Sinónimos:

Tridecafluoroheptanoic acid, Perfluoroheptanoic acid

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About This Item

Fórmula lineal:
CF3(CF2)5CO2H
Número de CAS:
375-85-9
Peso molecular:
364.06
Beilstein/REAXYS Number:
1808210
EC Number:
206-798-9
MDL number:
MFCD00039604
UNSPSC Code:
12352200
PubChem Substance ID:
24861023
NACRES:
NA.22

Quality Level

200

assay

≥97.0%

form

solid

refractive index

n20/D 1.306 (lit.)

bp

175 °C/742 mmHg (lit.)

mp

30 °C (lit.)

density

1.792 g/mL at 25 °C (lit.)

SMILES string

OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/C7HF13O2/c8-2(9,1(21)22)3(10,11)4(12,13)5(14,15)6(16,17)7(18,19)20/h(H,21,22)

InChI key

ZWBAMYVPMDSJGQ-UHFFFAOYSA-N

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Application

Perfluoroheptanoic acid can be used as a reactant:
  • For the fluoroalkylation of C-H bonds of aromatic compounds using Ni/SiO2 nanocatalyst.
  • To synthesize biphenylyl benzoates via Mitsunobu reaction.
  • To synthesize N-perfluoracyl β-thioamides from β-thio amines in the presence of methyl chloroformate.

pictograms

Health hazard
GHS08

signalword

Danger

Hazard Classifications

Repr. 1B - STOT RE 1

target_organs

Liver

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificados de análisis (COA)

Lot/Batch Number
BCCL3152
BCCG9250
BCCF9059
BCCB7951
BCBZ4967

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Bart B L Groen et al.
The Journal of clinical endocrinology and metabolism, 101(11), 3978-3988 (2016-11-05)
Skeletal muscle protein synthesis is highly responsive to food intake. It has been suggested that the postprandial increase in circulating insulin modulates the muscle protein synthetic response to feeding. The objective of the study was to investigate whether a greater
N Kudo et al.
Chemico-biological interactions, 134(2), 203-216 (2001-04-20)
Elimination in urine and feces was compared between four perfluorinated fatty acids (PFCAs) with different carbon chain length. In male rats, perfluoroheptanoic acid (PFHA) was rapidly eliminated in urine with the proportion of 92% of the dose being eliminated within
Mingxiao Zhao et al.
Molecular bioSystems, 13(4), 756-766 (2017-02-23)
After a large-scale radiological accident, early-response biomarkers to assess radiation exposure over a broad dose range are not only the basis of rapid radiation triage, but are also the key to the rational use of limited medical resources and to
Huangfang Xu et al.
Environment international, 143, 105952-105952 (2020-07-28)
Long-chain per- and polyfluoroalkyl substances (PFASs) and their short-chain alternatives have been produced and used extensively in China. However, it is unclear whether these compounds contribute to the risk of gestational diabetes mellitus (GDM) in women residing in contaminated areas.
Mikhail N Khrizanforov et al.
Dalton transactions (Cambridge, England : 2003), 45(30), 11976-11982 (2016-07-08)
We have developed Ni(III)-doped silica nanoparticles ([(bpy)xNi(III)]@SiO2) as a recyclable, low-leaching, and efficient oxidative functionalization nanocatalyst for aromatic C-H bonds. The catalyst is obtained by doping the complex [(bpy)3Ni(II)] on silica nanoparticles along with its subsequent electrooxidation to [(bpy)xNi(III)] without
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