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Merck

195731

Sigma-Aldrich

Iron(0) pentacarbonyl

greener alternative

Sinónimos:

Iron(0) carbonyl, Pentacarbonyliron(0)

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About This Item

Fórmula lineal:
Fe(CO)5
Número de CAS:
Peso molecular:
195.90
Número CE:
Número MDL:
Código UNSPSC:
12161600
ID de la sustancia en PubChem:
NACRES:
NA.22
En este momento no podemos mostrarle ni los precios ni la disponibilidad

densidad de vapor

6.74 (vs air)

Nivel de calidad

presión de vapor

35 mmHg ( 25 °C)
40 mmHg ( 30.3 °C)

temp. de autoignición

122 °F

idoneidad de la reacción

core: iron
reagent type: catalyst

características de los productos alternativos más sostenibles

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

índice de refracción

n20/D 1.5196 (lit.)

bp

103 °C (lit.)

mp

−20 °C (lit.)

densidad

1.49 g/mL at 25 °C (lit.)

categoría alternativa más sostenible

temp. de almacenamiento

2-8°C

cadena SMILES

[Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/5CO.Fe/c5*1-2;

Clave InChI

FYOFOKCECDGJBF-UHFFFAOYSA-N

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Descripción general

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Aplicación

Iron(0) pentacarbonyl can be used:
  • As an iron source to synthesize Fe-doped thin TiO2 films.[1]
  • As a ligand to synthesize complexes of gold(I) and Fe(CO)5,[2] silver and Fe(CO)5.[3]
Reactant for:
  • Addition reactions
  • Decomposition via photolysis
  • Preparation of magnetic Fe onion-like fullerene micrometer-sized particles of narrow size distribution via thermal decomposition
  • Preparation of a heptanuclear iron carbonyl cluster used in catalytic hydrosilane reduction of carboxamides

  • Precursor for preparation of Fe nanoparticles for photocatalytic hydrogen evolution under highly basic conditions

Pictogramas

FlameSkull and crossbones

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Flam. Liq. 2

Código de clase de almacenamiento

3 - Flammable liquids

Clase de riesgo para el agua (WGK)

WGK 1

Punto de inflamabilidad (°F)

5.0 °F - closed cup

Punto de inflamabilidad (°C)

-15 °C - closed cup

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Certificados de análisis (COA)

Lot/Batch Number

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Visite la Librería de documentos

Plasma enhanced chemical vapor deposition of iron doped thin dioxide films, their structure and photowetting effect.
Sobczyk-Guzenda A, et al.
Thin Solid Films, 589, 605-612 (2015)
Heterobimetallic Complexes Featuring Fe(CO)5 as a Ligand on Gold.
Wang G, et al.
Chemistry?A European Journal , 23(68), 17222-17226 (2017)
Heterobimetallic Silver-Iron Complexes Involving Fe(CO)5 Ligands
Wang G, et al.
Journal of the American Chemical Society, 139(40), 14292-14301 (2017)
Miguel D Ferrer et al.
The British journal of nutrition, 103(1), 69-76 (2009-11-04)
Our aim was to analyse the influence of variegate porphyria (VP) on the antioxidant defenses and markers of oxidative damage and inflammation in plasma and neutrophils and the effects of dietary supplementation with vitamins E and C on these parameters
Ioan Silaghi-Dumitrescu et al.
Journal of the American Chemical Society, 130(3), 901-906 (2008-01-01)
Density functional theory studies on a series of Fe2(CO)6(PX)2 derivatives show the tetrahedrane to be the most stable for the alkyl (X = Me, tBu), P-H (X = H), and chloro (X = Cl) derivatives. However, butterfly diradical and planar

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. Qual è il grado di purezza?

    1 answer
    1. This product is not tested for purity and is considered a general use item. Should the purity and additional analytical testing be required, see product 481718. A link to this product page, as well as a sample Certificate of Analysis are provided below:

      481718 Iron(0) Pentacarbonyl product page:
      https://www.sigmaaldrich.com/US/en/product/aldrich/481718

      Sample Certificate of Analysis:
      https://www.sigmaaldrich.com/certificates/sapfs/PROD/sap/certificate_pdfs/COFA/Q14/481718-BULKSHBQ5322.pdf

      Helpful?

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