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MilliporeSigma

208221

Sigma-Aldrich

Iodine monochloride

reagent grade, ≥95%

Sinónimos:

Chloroiodide

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$61.10
100 G
$183.00
250 G
$316.00

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5 G
$61.10
100 G
$183.00
250 G
$316.00

About This Item

Fórmula lineal:
ICl
Número de CAS:
Peso molecular:
162.36
Número CE:
Número MDL:
Código UNSPSC:
12352300
ID de la sustancia en PubChem:
NACRES:
NA.21

$61.10


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grado

reagent grade

Nivel de calidad

Ensayo

≥95%

Formulario

solid or liquid

bp

97.4 °C (lit.)

densidad

3.24 g/mL at 25 °C (lit.)

temp. de almacenamiento

2-8°C

cadena SMILES

ClI

InChI

1S/ClI/c1-2

Clave InChI

QZRGKCOWNLSUDK-UHFFFAOYSA-N

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Descripción general

Iodine monochloride is an interhalogen compound.[1] It forms various complexes with ethyl, isopropyl and t-butylbenzenes.[2] Electrically conducting solution of ICl is obtained on dissolution of ICl in polar solvents.[3] ICl is a green oxidizing agent and participates in the following transformations:[4]
  • aldose hemiacetals to the corresponding aldose lactones
  • diarylmethanols to the corresponding diarylmethanones
  • arylalkylmethanols to the corresponding arylalkylmethanones
  • dialkylmethanols to the corresponding dialkylmethanones

Aplicación

Iodine monochloride (ICl) may be employed as a reagent in the following processes:
  • Halogenation of methoxy and dimethoxybenzenes[3]
  • Synthesis of flavones.[5]
  • Preparation of 1-naphthaldehydes.[1]
It may be used as an iodinating agent in the conversion of alkylboranes to alkyl iodides.[6]

Pictogramas

CorrosionExclamation mark

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Órganos de actuación

Respiratory system

Código de clase de almacenamiento

8B - Non-combustible corrosive hazardous materials

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable


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Certificados de análisis (COA)

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Visite la Librería de documentos

Iodine Monochloride (ICl) as a Highly Efficient, Green Oxidant for the Oxidation of Alcohols to Corresponding Carbonyl Compounds
Wei, Peng, et al.
Synthetic Communications, 45.12, 1457-1470 (2015)
Synthesis of 1-naphthaldehydes via the cascade reactions of 1-phenylpent-4-yn-2-ols promoted by iodine monochloride
Li B, et al.
Tetrahedron Letters, 57.17, 1843-1846 (2016)
A mild and convenient procedure for conversion of alkenes into alkyl iodides via reaction of iodine monochloride with organoboranes.
Kabalka GW and Gooch III EE.
The Journal of Organic Chemistry, 45(18), 3578-3580 (1980)
Polymethylbenzene complexes of iodine and iodine monochloride.
Andrews LJ and Keefer RM.
Journal of the American Chemical Society, 74(18), 4500-4503 (1952)
Ultrasonic-assisted synthesis of flavones by oxidative cyclization of 2'-hydroxychalcones using iodine monochloride.
Lahyani A and Trabelsi M.
Ultrasonics Sonochemistry, 31, 626-630 (2016)

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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