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179906

Sigma-Aldrich

Tributylborane solution

1.0 M in THF

Sinónimos:

TBB, Tributylboron

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About This Item

Fórmula lineal:
[CH3(CH2)3]3B
Número de CAS:
122-56-5
Peso molecular:
182.15
MDL number:
MFCD00009423
UNSPSC Code:
12352001
PubChem Substance ID:
24850833

form

liquid

reaction suitability

reagent type: reductant

concentration

1.0 M in THF

density

0.834 g/mL at 25 °C

SMILES string

CCCCB(CCCC)CCCC

InChI

1S/C12H27B/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3

InChI key

CMHHITPYCHHOGT-UHFFFAOYSA-N

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Application

Reactant for:
  • Addition reactions for synthesis of phenyltrialkylborate salts
  • Boron-based multicomponent reactions for generation of substituted aziridines, oxazolidines, and pyrrolidines
  • Suzuki-Miyaura cross coupling of halopurines with trialkylboranes for the synthesis of adenosine A2A receptor antagonists
  • Multicomponent C-alkylation reactions with aromatic aldimines
  • One-pot alkylation-boration and electrophilic substitution

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system, Respiratory system

supp_hazards

EUH019

Storage Class

3 - Flammable liquids

wgk_germany

WGK 1

flash_point_f

1.4 °F

flash_point_c

-17 °C

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Certificados de análisis (COA)

Lot/Batch Number
SHBK6600
SHBG2799V
SHBB4583
13619HH
12927EU

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The Nicotine Metabolite Ratio (NMR, ratio of trans-3'-hydroxycotinine and cotinine), has previously been associated with CYP2A6 activity, response to smoking cessation treatments, and cigarette consumption. We searched for drug metabolizing enzyme and transporter (DMET) gene variation associated with the NMR
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After lung transplantation (LT), immunoglobulin (Ig) G plasma concentrations<6 g/L are common and correlate with an increased risk of chronic lung allograft dysfunction (CLAD) and a poorer survival. We conducted an open substitution intervention with nonspecific intravenous Ig (IVIg), in
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