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  • Heteropoly acid as a novel nitrene transfer agent: a facile and practical aziridination of olefins with Chloramine-T.

Heteropoly acid as a novel nitrene transfer agent: a facile and practical aziridination of olefins with Chloramine-T.

Chemical communications (Cambridge, England) (2004-04-08)
G D Kishore Kumar, Sundarababu Baskaran
ABSTRACT

Environmentally benign HPA is found to be an efficient catalyst for aziridination of olefins in the presence of inexpensive Chloramine-T as a nitrogen source: instantaneous at room temperature, requires only stoichiometric amount of olefin and no allyl amine side product.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Chloramine T trihydrate, ACS reagent, 98%
Sigma-Aldrich
Chloramine-T hydrate, 95%