80001
Zoxamide
certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Synonym(s):
3,5-Dichloro-N-(3-chloro-1-ethyl-1-methyl-2-oxopropyl)-4-methylbenzamide
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About This Item
Empirical Formula (Hill Notation):
C14H16Cl3NO2
CAS Number:
Molecular Weight:
336.64
Beilstein/REAXYS Number:
11413911
MDL number:
UNSPSC Code:
41116107
NACRES:
NA.24
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grade
certified reference material
TraceCERT®
Quality Level
product line
TraceCERT®
shelf life
limited shelf life, expiry date on the label
manufacturer/tradename
Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
format
neat
SMILES string
CCC(C)(NC(=O)c1cc(Cl)c(C)c(Cl)c1)C(=O)CCl
InChI
1S/C14H16Cl3NO2/c1-4-14(3,12(19)7-15)18-13(20)9-5-10(16)8(2)11(17)6-9/h5-6H,4,7H2,1-3H3,(H,18,20)
InChI key
SOUGWDPPRBKJEX-UHFFFAOYSA-N
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General description
This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Zoxamide is a benzamide fungicide applied to crops to control damage caused by oomycete pathogens and ascomycete fungi. It is used as veterinary pharmaceuticals in aquaculture and for the control of various fungal infections including blight in potatoes and tomatoes.
As per Regulation (EC) No 1107/2009, repealing the directive 91/414/ECC, zoxamide is approved for use in the European Union (EU). A maximum residue limit (MRL) of 0.02 mg/kg is applicable for the presence of zoxamide in fresh/frozen fruits, and tree nuts, in accordance with Regulation (EU) 2017/171.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Zoxamide is a benzamide fungicide applied to crops to control damage caused by oomycete pathogens and ascomycete fungi. It is used as veterinary pharmaceuticals in aquaculture and for the control of various fungal infections including blight in potatoes and tomatoes.
As per Regulation (EC) No 1107/2009, repealing the directive 91/414/ECC, zoxamide is approved for use in the European Union (EU). A maximum residue limit (MRL) of 0.02 mg/kg is applicable for the presence of zoxamide in fresh/frozen fruits, and tree nuts, in accordance with Regulation (EU) 2017/171.
Application
The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The zoxamide CRM may also find the following uses:
The zoxamide CRM may also find the following uses:
- Determination of zoxamide and its two acid metabolites in ginseng roots using ultra-performance liquid chromatography-tandem mass spectrometer (UPLC-MS/MS)
- Determination of zoxamide in wine samples by reverse-phase high-performance liquid chromatography (RP-HPLC)
- To evaluate the efficacy of post-harvest applications of zoxamide in reducing potato tuber rots caused by oomycetes at harvest
- A systemic assessment of zoxamide enantiomers at the enantiomeric level
- To assess the influence of mancozeb, zoxamide, and copper oxychloride fungicide treatments on manganese, zinc, copper, cadmium, and lead concentrations in Sicilian red wines, grapes, marcs, and grape stalks using derivative stripping chronopotentiometry
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Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
Legal Information
TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Warning
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1A
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Lynda V Podhorniak
Journal of agricultural and food chemistry, 62(17), 3702-3709 (2014-02-21)
A miniaturized residue method was developed for the analysis of the fungicide zoxamide and its metabolites in dried ginseng root. The zoxamide metabolites, 3,5-dichloro-1,4-benzenedicarboxylic acid (DCBC) and 3,5-dichloro-4-hydroxymethylbenzoic acid (DCHB), are small acid molecules that have not been previously extracted
Xinglu Pan et al.
The Science of the total environment, 733, 139069-139069 (2020-05-24)
Zoxamide is a recently discovered chiral fungicide that applied to agricultural production, but the potential environmental risk may be underestimated because the risk posed by either enantiomer has not been adequately assessed. Therefore, systemic evaluation of zoxamide was first carried
L La Pera et al.
Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment, 25(3), 302-313 (2008-03-04)
The aim was to assess the influence of mancozeb, zoxamide and copper oxychloride fungicide treatments on Mn, Zn, Cu, Cd and Pb concentrations in Sicilian red wines, grapes, marcs and grape stalks. The experimentation was carried out over two crop
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