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A6756

Sigma-Aldrich

Sodium arsenate dibasic heptahydrate

≥98.0%

Synonym(s):

Disodium hydrogen arsenate heptahydrate, di-Sodium hydrogen arsenate heptahydrate

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About This Item

Linear Formula:
Na2HAsO4 · 7H2O
CAS Number:
10048-95-0
Molecular Weight:
312.01
MDL number:
MFCD00149179
UNSPSC Code:
12352302
PubChem Substance ID:
24891135
NACRES:
NA.21

assay

≥98.0%

form

powder

reaction suitability

reagent type: catalyst
core: arsenic

pH

8.5-9.0 (25 °C, 50 g/L)

SMILES string

O.O.O.O.O.O.O.[Na+].[Na+].O[As]([O-])([O-])=O

InChI

1S/AsH3O4.2Na.7H2O/c2-1(3,4)5;;;;;;;;;/h(H3,2,3,4,5);;;7*1H2/q;2*+1;;;;;;;/p-2

InChI key

KOLXPEJIBITWIQ-UHFFFAOYSA-L

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General description

Sodium arsenate dibasic heptahydrate (As(V)) is an arsenic compound.

Application

Sodium arsenate dibasic heptahydrate may be used as a reference standard for the quantification of arsenic compounds in rice- and seafood-based samples by ion chromatography-inductively coupled plasma/ mass spectrometry. The samples for analysis were prepared by ultrasonic-assisted enzymatic extraction (UAEE).

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Validation of a method for arsenic speciation in food by ion chromatography-inductively coupled plasma/mass spectrometry after ultrasonic-assisted enzymatic extraction.
Dufailly V, et al.
Journal of AOAC (Association of Official Analytical Chemists) International, 94(3), 947-958 (2011)
Martin P Pothier et al.
Frontiers in microbiology, 9, 2310-2310 (2018-10-20)
Despite its high toxicity and widespread occurrence in many parts of the world, arsenic (As) concentrations in decentralized water supplies such as domestic wells remain often unquantified. One limitation to effective monitoring is the high cost and lack of portability
Shugo Suzuki et al.
Toxicology, 299(2-3), 155-159 (2012-06-06)
Inorganic arsenic is a known human carcinogen, inducing tumors of the skin, urinary bladder and lung. It is metabolized to organic methylated arsenicals. 2,3-Dimercaptopropane-1-sulfonic acid (DMPS), a chelating agent, is capable of reducing pentavalent arsenicals to the trivalent state and
Takayuki Watanabe et al.
Archives of toxicology, 85(6), 577-588 (2011-05-04)
It has been suggested that arsenic (+3 oxidation state) methyltransferase (AS3MT) plays a critical role in methylation of arsenic, and that arsenic-glutathione conjugate is a substrate for AS3MT-catalyzed methylation of arsenic. However, the mechanism of arsenic methylation in cells is
Ruilong Liu et al.
Nature communications, 10(1), 991-991 (2019-03-03)
6-Phosphogluconate dehydrogenase (6PGD) is a key enzyme that converts 6-phosphogluconate into ribulose-5-phosphate with NADP+ as cofactor in the pentose phosphate pathway (PPP). 6PGD is commonly upregulated and plays important roles in many human cancers, while the mechanism underlying such roles
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