Skip to Content
MilliporeSigma
All Photos(3)

Documents

A7149

Sigma-Aldrich

Ammonium thiocyanate

powder

Synonym(s):

Ammonium rhodanide

Sign Into View Organizational & Contract Pricing
All Photos(3)

About This Item

Linear Formula:
NH4SCN
CAS Number:
1762-95-4
Molecular Weight:
76.12
Beilstein/REAXYS Number:
3595135
EC Number:
217-175-6
MDL number:
MFCD00011428
UNSPSC Code:
12352300
eCl@ss:
38060604
PubChem Substance ID:
329770916
NACRES:
NA.55

vapor pressure

0.000114 hPa ( 20 °C)

assay

≥98% NaOH basis (titration)

form

powder

color

white

pH

4.8 (20.1 °C, 1070 g/L)

mp

152-154 °C (lit.)

solubility

water: soluble 76.1 g/L at 20 °C

SMILES string

N.SC#N

InChI

1S/CHNS.H3N/c2-1-3;/h3H;1H3

InChI key

SOIFLUNRINLCBN-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

Ammonium thiocyanate is an ammonium salt commonly used for thiocyanation reaction of organic compounds.

Application

Ammonium thiocyanate (ATC) has been used for the preparation of epidermal sheets separated from the skin of the K14E7 mouse for immunofluorescence staining.
It may be used the synthesis of the following:
Ammonium thiocyanate (ATC) may be used the synthesis of the following:
  • Graphitic carbon nitride.
  • Three-dimensional nitrogen and sulfur co-doped graphene frameworks (N/S-GFs).
  • Substituted 2-aminothiazole derivatives by reacting with α-halo ketone carbonyls in the presence of N-methylimidazole.
  • Thiiranes from corresponding oxiranes in the presence of LiBF4.
  • 1,2,4-triazole-3-thiones by a multi-component reaction with benzohydrazide acid and acid chloride in the absence of solvent.

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1

supp_hazards

EUH032

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Nor Malia Abd Warif et al.
PloS one, 10(5), e0127155-e0127155 (2015-05-21)
It has previously been shown that expression of human papillomavirus type 16 (HPV) E7 in epidermis causes hyperplasia and chronic inflammation, characteristics of pre-malignant lesions. Importantly, E7-expressing epidermis is strongly immune suppressed and is not rejected when transplanted onto immune
Thiocyanation of aromatic and heteroaromatic compounds using ammonium thiocyanate and I2O5.
Wu J, et al.
Synthetic Communications, 38(14), 2367-2373 (2008)
NBS or DEAD as effective reagents in α-thiocyanation of enolizable ketones with ammonium thiocyanate.
Reddy BVS, et al.
Tetrahedron Letters, 52(13), 1432-1435 (2011)
Regioselective thiocyanation of aromatic and heteroaromatic compounds using ammonium thiocyanate and oxone.
Wu G, et al.
Tetrahedron Letters, 46(35), 5831-5834 (2005)
Convenient and simple synthesis of 2-aminothiazoles by the reaction of α-halo ketone carbonyls with ammonium thiocyanate in the presence of N-methylimidazole.
Meshram HM, et al.
Tetrahedron Letters, 53(39), 5265-5269 (2012)
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service