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Sigma-Aldrich

Copper(II) sulfate

puriss. p.a., anhydrous, ≥99.0% (RT)

Synonym(s):

Cupric sulfate

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About This Item

Linear Formula:
CuSO4
CAS Number:
Molecular Weight:
159.61
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:

vapor pressure

7.3 mmHg ( 25 °C)

grade

puriss. p.a.

assay

≥99.0% (RT)

form

powder

impurities

≤0.005% total nitrogen (N)

loss

≤1.0% loss on drying, 250 °C

pH

3.5-4.5 (20 °C, 50 g/L)

mp

200 °C (dec.) (lit.)

density

3.603 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤20 mg/kg

cation traces

Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Fe: ≤50 mg/kg
K: ≤50 mg/kg
Mg: ≤20 mg/kg
Mn: ≤5 mg/kg
Na: ≤50 mg/kg
Ni: ≤50 mg/kg
Pb: ≤50 mg/kg
Zn: ≤50 mg/kg

application(s)

environmental

SMILES string

[Cu++].[O-]S([O-])(=O)=O

InChI

1S/Cu.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+2;/p-2

InChI key

ARUVKPQLZAKDPS-UHFFFAOYSA-L

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General description

Copper(II) sulfate (CuSO4) is an anhydrous copper(II) salt. It can be synthesized from CuSO4.5H2O, via dehydration. Copper(II) sulfate adsorbed on silica gel participates in the conversion of secondary and tertiary alcohols to olefins. Copper(II) sulfate-alumina has been employed as a solid-reagent system during the synthesis of benzils.

Application

Copper(II) sulfate (CuSO4) may be employed as metal source in the synthesis of copper oxide (CuO) hollow nanospheres.

pictograms

Exclamation markEnvironment

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Chemistry Letters (Jpn), 43(9), 1426-1428 (2014)
Dehydration of alcohols catalyzed by copper (II) sulfate adsorbed on silica gel.
Nishiguchi T, et al.
Tetrahedron Letters, 28(39), 4565-4568 (1987)
Solid State Oxidation of Benzoins on Alumina-Supported Copper (II) Sulfate under Microwave Irradiation?.
Varma RS.
J. Chem. Res. Synop., 6, 324-325 (1998)
Copper (II) Sulfate.
Hoffman RV, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2007)

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