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96602

Sigma-Aldrich

Bis(cyclopentadienyl)zirconium bis(trifluoromethanesulfonate) tetrahydrofuran complex

purum, ≥97.0%

Synonym(s):

Di(cyclopentadienyl)zirconium bis(trifluoromethanesulfonate) THF complex, Zirconocene bis(trifluoromethanesulfonate) THF complex

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About This Item

Empirical Formula (Hill Notation):
C12H10F6O6S2Zr · C4H8O
CAS Number:
Molecular Weight:
591.65
MDL number:
UNSPSC Code:
12352300

grade

purum

assay

≥97.0%

SMILES string

[Zr++].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2.C3CCOC3.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F

Other Notes

Catalyst for Diels-Alder reactions; Catalyst for Mukaiyama cross-aldol reactions

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

174.2 °F - closed cup

flash_point_c

79 °C - closed cup

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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T.K. Hollis et al.
Tetrahedron Letters, 33, 6423-6423 (1992)
T.K. Hollis et al.
Organometallics, 11, 2745-2745 (1992)

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