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66680

Sigma-Aldrich

(S,S)-2,2′-Methylenebis(4-tert-butyl-2-oxazoline)

purum, ≥95.0% (sum of enantiomers, GC)

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About This Item

Empirical Formula (Hill Notation):
C15H26N2O2
CAS Number:
Molecular Weight:
266.38
Beilstein/REAXYS Number:
4190673
MDL number:
UNSPSC Code:
12352000

grade

purum

assay

≥95.0% (sum of enantiomers, GC)

optical activity

[α]20/D −114±3°, c = 0.5% in chloroform stab. with amylenes

mp

50-53 °C (lit.)
50-53 °C

storage temp.

2-8°C

SMILES string

CC(C)(C)[C@H]1COC(CC2=N[C@H](CO2)C(C)(C)C)=N1

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

Catalyst for the enantioselective cyclopropanation of olefins with diazoesters[1][2]

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R.E. Lowenthal et al
Tetrahedron Letters, 31, 6005-6005 (1990)
D.A. Evans et al.
Journal of the American Chemical Society, 113, 726-726 (1991)

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