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41663

Sigma-Aldrich

1,3-Dimethyl-1,1,3,3-tetraphenyldisilazane

≥98.0% (NT)

Synonym(s):

1,1,3,3-Tetraphenyl-1,3-dimethyldisilazane, TPDMDS

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About This Item

Linear Formula:
[CH3Si(C6H5)2]2NH
CAS Number:
Molecular Weight:
409.67
Beilstein/REAXYS Number:
2952534
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

assay

≥98.0% (NT)

form

solid

mp

87-89 °C (lit.)
87-89 °C

SMILES string

C[Si](N[Si](C)(c1ccccc1)c2ccccc2)(c3ccccc3)c4ccccc4

InChI

1S/C26H27NSi2/c1-28(23-15-7-3-8-16-23,24-17-9-4-10-18-24)27-29(2,25-19-11-5-12-20-25)26-21-13-6-14-22-26/h3-22,27H,1-2H3

InChI key

YFONAHAKNVIHPT-UHFFFAOYSA-N

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General description

1,3-Dimethyl-1,1,3,3-tetraphenyldisilazane is a silylating reagent, used for the hydrophobization of glass or silica surfaces.

Other Notes

For the deactivation of glass capillary columns by persilylation

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Silicon in Polymer Synthesis (2012)
Christopher A Girkin et al.
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Concentration modulation by thermal decomposition for multiplex gas chromatography.
J R Valentin et al.
HRC & CC. Journal of high resolution chromatography & chromatography communications, 6, 621-622 (1983-11-01)

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