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33897

Supelco

Thiacloprid-amide

PESTANAL®, analytical standard

Synonym(s):

[3-(6-Chloro-3-pyridylmethyl)thiazolidin-2-ylidene]urea

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About This Item

Empirical Formula (Hill Notation):
C10H11ClN4OS
CAS Number:
676228-91-4
Molecular Weight:
270.74
MDL number:
MFCD08690611
UNSPSC Code:
41116107
PubChem Substance ID:
329754533
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

NC(=O)\N=C1/SCCN1Cc2ccc(Cl)nc2

InChI

1S/C10H11ClN4OS/c11-8-2-1-7(5-13-8)6-15-3-4-17-10(15)14-9(12)16/h1-2,5H,3-4,6H2,(H2,12,16)/b14-10-

InChI key

LEZHOZPJYAQQNU-UVTDQMKNSA-N

General description

Thiacloprid-amide is a metabolite of thiacloprid, an insecticide belonging to the class of neonicotinoids.[1] It is primarily used for foliar applications for pest control in arable crops, orchards, vegetables, and other crops.[1]

Find more information here: Neonicotinoids

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Thiacloprid-amide may be used as an analytical reference standard for the determination of the analyte in:
  • Green pepper/tomato samples using water based extraction and solid-phase extraction followed by liquid chromatography coupled to tandem mass spectrometry (LC-MS/MS).[2]
  • Honey bees and honey samples using solid-phase extraction followed by liquid chromatography coupled to tandem mass spectrometry (LC-MS/MS).[3]

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
BCBW2125

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Determination of neonicotinoid insecticides and their metabolites in honey bee and honey by liquid chromatography tandem mass spectrometry.
Gbylik-Sikorska M, et al.
Journal of Chromatography. B, Biomedical Sciences and Applications, 990(7), 132-140 (2015)
Water-based extraction and liquid chromatography-tandem mass spectrometry analysis of neonicotinoid insecticides and their metabolites in green pepper/tomato samples.
Iwafune T, et al.
Journal of Agricultural and Food Chemistry, 62(13), 2790-2796 (2014)
Performance of honey bee colonies under a long-lasting dietary exposure to sublethal concentrations of the neonicotinoid insecticide thiacloprid.
Siede R, et al.
Pest Management Science, 73(7), 1334-1344 (2017)
Marc Le Vée et al.
Journal of biochemical and molecular toxicology, 33(10), e22379-e22379 (2019-08-01)
The interactions of six neonicotinoid pesticides and one neonicotinoid metabolite with drug transporters have been characterized in vitro. Acetamiprid, clothianidin, imidacloprid, nitenpyram, thiacloprid and its metabolite thiacloprid amide, and thiamethoxam, each used at 100 µM, did not impair activity of the
Kouji H Harada et al.
PloS one, 11(1), e0146335-e0146335 (2016-01-06)
Neonicotinoids, which are novel pesticides, have entered into usage around the world because they are selectively toxic to arthropods and relatively non-toxic to vertebrates. It has been suggested that several neonicotinoids cause neurodevelopmental toxicity in mammals. The aim was to

Protocols

Neonicotinoids

Learn more about Neonicotinoids - active substances used in plant protection products to control harmful insects.

Neonicotinoids Ban: Impact on Plant Material

Analysis of banned neonicotinoid insecticides from dandelion blossoms using QuEChERS and LC-MS.

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