234672

2,2′:6′,2′′-Terpyridine

98%

• Synonym(s): α,α′,α″-Tripyridyl, 2,6-Di(2-pyridyl)pyridine
• Empirical Formula (Hill Notation): C₁₅H₁₁N₃
• CAS Number: 1148-79-4
• Molecular Weight: 233.27
• Beilstein/REAXYS Number: 11199
• EC Number: 214-559-5
• MDL number: MFCD00006213
• UNSPSC Code: 12352100
• PubChem Substance ID: 57648035
• NACRES: NA.21

Properties

• Quality Level: 200
• assay: 98%
• form: solid
• mp: 89-91 °C (lit.)
• SMILES string: c1ccc(nc1)-c2cccc(n2)-c3ccccn3
• InChI: 1S/C15H11N3/c1-3-10-16-12(6-1)14-8-5-9-15(18-14)13-7-2-4-11-17-13/h1-11H
• InChI key: DRGAZIDRYFYHIJ-UHFFFAOYSA-N

Description

General description

2,2′:6′,2′′;-Terpyridine is a tridentate ligand that can be prepared in two steps, starting with 2-acetylpyridine. It coordinates with metal centers to form complexes. It is also utilized in the synthesis of chiral derivatives for asymmetric catalysis.

Application

Due to the presence of three near-coplanar nitrogen donor atoms, 2,2′:6′,2′′;-terpyridine may be used as a metal-binding domain to form metallo-supramolecular structures.

Safety Information

• pictograms: GHS06,GHS05
• signalword: Danger
• hcodes: H300 + H310,H315,H318,H335
• pcodes: P261 - P262 - P280 - P301 + P310 - P302 + P352 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 1 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges