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P29006

Sigma-Aldrich

Phenylphosphonic acid

98%

Synonym(s):

Benzene phosphonic acid

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About This Item

Linear Formula:
C6H5P(O)(OH)2
CAS Number:
1571-33-1
Molecular Weight:
158.09
Beilstein/REAXYS Number:
2245168
EC Number:
216-388-1
MDL number:
MFCD00002136
UNSPSC Code:
12352300
PubChem Substance ID:
24898371
NACRES:
NA.23

assay

98%

form

crystals

mp

162-164 °C (lit.)

SMILES string

OP(O)(=O)c1ccccc1

InChI

1S/C6H7O3P/c7-10(8,9)6-4-2-1-3-5-6/h1-5H,(H2,7,8,9)

InChI key

QLZHNIAADXEJJP-UHFFFAOYSA-N

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Application

Additive used with Noyori's catalyst for oxidation of sulfides to sulfones.

Noyori Oxidation (Sodium Tungstate Dihydrate, Hydrogen Peroxide, Methyltri-n-octylammonium Hydrogen Sulfate, Phosphonic Acid)
Self assembled monolayers (SAMs)of phenylphosphonic acid may be used to make the interface between organic semiconductors and transparent conductive oxides. The acid may be used to functionalize titania particles. Additive used with Noyorι¢s catalyst for greener oxidation of sulfides to sulfones.

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

hcodes

H302,H314

Hazard Classifications

Acute Tox. 4 Oral - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Zhaohui Cui et al.
Langmuir : the ACS journal of surfaces and colloids, 26(1), 179-182 (2009-08-04)
The in situ crystallization technique has been utilized to fabricate zirconium phenylphosphonate (ZrPP) films with their hexagonal crystallite perpendicular to the copper substrate. The micro/nano roughness surface structure, as well as the intrinsic hydrophobic characteristic of the surface functional groups
Christel Gervais et al.
Magnetic resonance in chemistry : MRC, 42(5), 445-452 (2004-04-20)
1H, 13C, 17O and 31P NMR parameters, including chemical shift tensors and quadrupolar parameters for 17O, were calculated for phenylphosphonic acid, C6H5PO(OH)2, under periodic boundary conditions. The results are in very good agreement with experimental data and permit the unambiguous
K Hendrich et al.
Journal of magnetic resonance. Series B, 105(3), 225-232 (1994-11-01)
Spatial localization with the spectroscopic imaging technique is normally implemented with the Fourier-transform approach, yielding rectangular voxels, with potentially significant cross-voxel contamination. Multidimensional Fourier-series window (FSW) is an alternate approach that generates single voxels of predetermined shape, with minimal out-of-voxel
M W Fryer et al.
Journal of muscle research and cell motility, 18(2), 161-167 (1997-04-01)
The rate, magnitude and pharmacology of inorganic phosphate (Pi) transport into the sarcoplasmic reticulum were estimated in single, mechanically skinned skeletal muscle fibres of the rat. This was done, indirectly, by using a technique that measured the total Ca2+ content
Jannie P Wijnen et al.
PloS one, 9(7), e102256-e102256 (2014-07-19)
To assess the ability of a polarization transfer (PT) magnetic resonance spectroscopy (MRS) technique to improve the detection of the individual phospholipid metabolites phosphocholine (PC), phosphoethanolamine (PE), glycerophosphocholine (GPC), and glycerophosphoethanolamine (GPE) in vivo in breast tumor xenografts. The adiabatic
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