92733
Methyl 3-trimethylsiloxy-2-butenoate
technical, ~86% (trans + ~10% cis)
Synonym(s):
3-Trimethylsiloxy-2-butenoic acid methyl ester, Methyl 3-(trimethylsiloxy)crotonate, Methyl acetoacetate enol trimethylsilylether
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About This Item
Empirical Formula (Hill Notation):
C8H16O3Si
CAS Number:
Molecular Weight:
188.30
Beilstein/REAXYS Number:
2356944
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
grade
technical
assay
~86% (trans + ~10% cis)
refractive index
n20/D 1.447
bp
43-45 °C/0.3 mmHg (lit.)
density
0.966 g/mL at 20 °C (lit.)
storage temp.
2-8°C
SMILES string
COC(=O)\C=C(/C)O[Si](C)(C)C
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T.H. Chan et al.
Journal of the Chemical Society. Chemical Communications, 578-578 (1979)
K. Yamamoto et al.
Chemistry Letters (Jpn), 649-649 (1978)
P. Brownbridge et al.
Tetrahedron Letters, 4437-4437 (1979)
T. Veysoglu et al.
Tetrahedron Letters, 22, 1303-1303 (1981)
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