Skip to Content
MilliporeSigma
All Photos(1)

Key Documents

View All Documentation

923508

Sigma-Aldrich

(iPrMPhos)PdCl2

1:1 complex with CH2Cl2, ≥95%

Synonym(s):

1-Diadamantylphosphino-1′-diisopropylphosphinoferrocene palladium dichloride

Sign Into View Organizational & Contract Pricing

Select a Size

100 MG
$79.21
500 MG
$236.50

$79.21

List Price$92.10Save 14%

Estimated to ship onApril 12, 2025

Request a Bulk Order
All Photos(1)

Select a Size

Change View
100 MG
$79.21
500 MG
$236.50

About This Item

Empirical Formula (Hill Notation):
C36H52Cl2FeP2Pd
Molecular Weight:
779.92
UNSPSC Code:
12352103
NACRES:
NA.22

$79.21

List Price$92.10Save 14%

Estimated to ship onApril 12, 2025

Request a Bulk Order

Quality Level

100

assay

≥95%

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

SMILES string

ClCCl.[Cl-][Pd+2]1([Cl-])[P](C(C)C)(C(C)C)[C-]23[CH]4=[CH]5[CH]6=[CH]2[Fe+2]56789%1043[CH]=%11[CH]%10=[CH]9[C-]8([CH]%117)[P]1(C%12%13CC%14CC(CC(C%14)C%12)C%13)C%15%16CC%17CC(CC(C%17)C%15)C%16

InChI

InChI=1S/C25H34P.C11H18P.CH2Cl2.2ClH.Fe.Pd/c1-2-4-23(3-1)26(24-11-17-5-18(12-24)7-19(6-17)13-24)25-14-20-8-21(15-25)10-22(9-20)16-25;1-9(2)12(10(3)4)11-7-5-6-8-11;2-1-3;;;;/h1-4,17-22H,5-16H2;5-10H,1-4H3;1H2;2*1H;;/q2*-1;;;;2*+2/p-2

InChI key

JBKBIWGRUZQRBH-UHFFFAOYSA-L

Application

(iPrMPhos)PdCl2 is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (iPrMPhos)PdCl2 can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp2-Csp3 coupling. Demonstrated Csp2-Csp3 couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR2)).

Learn more about MPhos ligands and catalysts

Other Notes

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp2–Csp3 Couplings

related product

Product No.
Description
Pricing

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

It looks like we've run into a problem, but you can still download Certificates of Analysis from our Documents section.

If you need assistance, please contact Customer Support.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Articles

MPhos Ligands & Catalysts

YPhos ligands facilitate palladium-catalyzed coupling reactions of aryl chlorides under mild conditions with short reaction times.

Questions

Reviews

No rating value

Active Filters

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service