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912522

Sigma-Aldrich

Adamantanyl 2,2-diiodoacetate

≥95%

Synonym(s):

Suero cyclopropanation reagent

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About This Item

Empirical Formula (Hill Notation):
C12H16I2O2
CAS Number:
Molecular Weight:
446.06
UNSPSC Code:
12352200

assay

≥95%

form

powder or crystals

reaction suitability

reaction type: C-C Bond Formation

mp

94-95 °C

storage temp.

2-8°C

Application

Adamantanyl 2,2-diiodoacetate is a photocyclopropanation reagent capable of late-stage functionalization. The cyclopropanation of styrenes proceeds in the presence of visible light, without the need of a photocatalyst.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Legal Information

This product is not available in Europe.

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Pricing

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

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A transition-metal-free & diazo-free styrene cyclopropanation
Herraiz A G and Suero M G
Chemical Science, 10, 9374-9379 (2019)

Related Content

The Suero research group has developed new catalytic methods involving conceptually-novel radical carbenoids, carbyne equivalents, and metal-carbynoids and studied their behavior towards fine & feedstock chemicals as well as medically relevant agents.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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