Skip to Content
MilliporeSigma
All Photos(2)

Documents

903698

Sigma-Aldrich

1-Isopropyl-4-methyl-5-norbornene

Synonym(s):

1-Isopropyl-4-methylbicyclo[2.2.1]hept-2-en

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Empirical Formula (Hill Notation):
C11H18
CAS Number:
2237928-12-8
Molecular Weight:
150.26
UNSPSC Code:
12352200

form

liquid

reaction suitability

reaction type: C-H Activation
reagent type: catalyst

storage temp.

2-8°C

Application

1-Isopropyl-4-methyl-5-norbornene is a norbornene ligand developed in the lab of Guanbing Dong for us in norbornene/palladium catalysis. The catalytic system of 1-Isopropyl-4-methyl-5-norbornene, [PdCl(allyl)]2 (683396), and RuPhos (663131) can be used for the site-selective ortho functionalization of aryl iodides.1

Other Notes

Complementary site-selectivity in arene functionalization enabled by overcoming the ortho constraint in palladium/norbornene catalysis

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Jianchun Wang et al.
Nature chemistry, 10(8), 866-872 (2018-06-27)
Achieving site-selectivity in arene functionalization that is complementary to the site-selectivity from electrophilic aromatic substitution reactions has been a long-standing quest in organic synthesis. Palladium/norbornene cooperative catalysis potentially offers a unique approach to this problem, but its use has been

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service