Skip to Content
MilliporeSigma
All Photos(2)

Key Documents

View All Documentation

900717

Sigma-Aldrich

N-((1S,2S)-1-((R)-4-Isopropyl-4,5-dihydrooxazol-2-yl)-2-methylbutyl)acetamide

≥95%

Synonym(s):

Chiral APAO ligand

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Empirical Formula (Hill Notation):
C13H24N2O2
Molecular Weight:
240.34
UNSPSC Code:
12352200
NACRES:
NA.22

assay

≥95%

form

powder

reaction suitability

reaction type: C-H Activation
reagent type: catalyst

color

white

functional group

amide

storage temp.

2-8°C

SMILES string

CC(C)[C@H]1N=C([C@@H](NC(C)=O)[C@@H](CC)C)OC1

Application

Chiral bidentate ligand developed by Jin-Quan Yu′s lab for enantioselective borylation of C(sp3)–H bonds. This acetyl-protected aminomethyl oxazoline (APAO) ligand was demonstrated to be compatible with carbocyclic substrates with both α-tertiary and α-quaternary carbon centers.

Other Notes

Pd(II)-Catalyzed Enantioselective C(sp3)–H Borylation

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

It looks like we've run into a problem, but you can still download Certificates of Analysis from our Documents section.

If you need assistance, please contact Customer Support.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Related Content

Yu Group – Prof. Product Portal

Yu program focuses on efficient C–H bond activation for drug synthesis, using simple starting materials.

Questions

Reviews

No rating value

Active Filters

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service