809098

Sodium 2-Naphthalenemethanesulfinate

• Empirical Formula (Hill Notation): C₁₁H₉NaO₂S
• Molecular Weight: 228.24
• UNSPSC Code: 12352200
• PubChem Substance ID: 329769137
• NACRES: NA.22

Properties

• form: powder
• reaction suitability: reaction type: C-C Bond Formation; reaction type: C-H Activation; reagent type: catalyst
• functional group: sulfinic acid
• SMILES string: O=S(O[Na])CC1=CC2=CC=CC=C2C=C1
• InChI: 1S/C11H10O2S.Na/c12-14(13)8-9-5-6-10-3-1-2-4-11(10)7-9;/h1-7H,8H2,(H,12,13);/q;+1/p-1
• InChI key: FIUBTIUINOLGCP-UHFFFAOYSA-M

Description

General description

Sodium 2-Naphthalenemethanesulfinate is a sulfinate reagent bearing a napthalene moiety.

Application

The following Baran Sulfinate is a part of a toolbox of diversification reagents, which are ideal for the late-stage functionalization of nitrogen-containing heterocycles. The regioselectivity can be effectively tuned by modification of the pH and solvent selection.

Other Notes

Diversinates^™: Any-Stage Functionalization of (Hetero)aromatic Scaffolds

Legal Information

Diversinates is a trademark of Sigma-Aldrich Co. LLC

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable