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Fe/ppm Pd for Suzuki-Miyaura Cross-Couplings

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About This Item

EC Number:
231-729-4
UNSPSC Code:
12161600

form

powder, crystals or chunks

reaction suitability

core: iron
reaction type: Cross Couplings
reagent type: catalyst

Application

Nanoparticles (NPs) of this material contain parts per million (ppm) levels of Pd. The NPs can catalyze Suzuki-Miyaura (SM) reactions, including cases involving highly challenging reaction partners. Nano micelles are employed to both solubilize and deliver the reaction partners to the Fe/ppm Pd catalyst resulting in C-C bond formation.

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Product No.
Description
Pricing

902292

EvanPhos, ≥95%

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Sachin Handa et al.
Science (New York, N.Y.), 349(6252), 1087-1091 (2015-09-05)
Most of today's use of transition metal-catalyzed cross-coupling chemistry relies on expensive quantities of palladium (Pd). Here we report that nanoparticles formed from inexpensive FeCl3 that naturally contains parts-per-million (ppm) levels of Pd can catalyze Suzuki-Miyaura reactions, including cases that
When Does Organic Chemistry Follow Nature?s Lead and ?Make the Switch?.
Lipshutz B H
The Journal of Organic Chemistry, 82(6), 2806-2816 (2017)
New surfactants for chemistry in water.
Krause N
Current opinion in green and sustainable chemistry., 7, 18-22 (2017)
Switching from organic solvents to water at an industrial scale.
Parmentier M, et al.
Current opinion in green and sustainable chemistry., 7, 13-17 (2017)

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Lipshutz Group – Professor Product Portal

Prof. Bruce Lipshutz and co-workers have developed designer surfactants to allow several classes of transformations (e.g. Suzuki-Miyaura, Olefin Metathesis, 1,4-Addition to Enones, etc.) to be performed in water.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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