794171

9-Mesityl-10-methylacridinium tetrafluoroborate

• Synonym(s): 9-Mesityl-10-methylacridinium tetrafluoroborate, 10-Methyl-9-(2,4,6-trimethylphenyl)acridinium tetrafluoroborate
• Empirical Formula (Hill Notation): C₂₃H₂₂BF₄N
• CAS Number: 1442433-71-7
• Molecular Weight: 399.23
• UNSPSC Code: 12161600
• PubChem Substance ID: 329768429
• NACRES: NA.22

Properties

• form: solid
• Quality Level: 100
• reaction suitability: core: acridinium; reaction type: Photocatalysis; reagent type: catalyst
• photocatalyst activation: 450 nm
• SMILES string: CC(C=C1C)=CC(C)=C1C2=C3C(C=CC=C3)=[N+](C)C4=CC=CC=C42.F[B-](F)(F)F
• InChI: 1S/C23H22N.BF4/c1-15-13-16(2)22(17(3)14-15)23-18-9-5-7-11-20(18)24(4)21-12-8-6-10-19(21)23;2-1(3,4)5/h5-14H,1-4H3;/q+1;-1
• InChI key: KKMWMXQQOIIJIZ-UHFFFAOYSA-N

Description

Application

Catalyst has been reported by Nicewicz and coworkers to mediate myriad transformations through Photoredox Catalysis. The following applications include the anti-Markovnikov hydroamination of alkenes and addition of carboxylic acids to alkenes and the hydrotrifluoromethylation of styrenes using the Langlois reagent (743232).

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Anti-Markovnikov Hydroamination of Alkenes Catalyzed by an Organic Photoredox System

Direct Catalytic Anti-Markovnikov Addition of Carboxylic Acids to Alkenes

Catalytic hydrotrifluoromethylation of styrenes and unactivated aliphatic alkenes via an organic photoredox system

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable