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745146

Sigma-Aldrich

9-Methyl-9H-fluorene-9-carbonyl-13C chloride

≥97.0% (GC)

Synonym(s):

13COgen

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250 MG
$416.00
1 G
$1,380.00

$416.00

Estimated to ship onMarch 28, 2025

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250 MG
$416.00
1 G
$1,380.00

About This Item

Empirical Formula (Hill Notation):
13CC14H11ClO
CAS Number:
1072315-89-9
Molecular Weight:
243.69
MDL number:
MFCD18839249
UNSPSC Code:
12352005
PubChem Substance ID:
329764967
NACRES:
NA.22
form:
solid
assay:
≥97.0% (GC)

$416.00

Estimated to ship onMarch 28, 2025

Request a Bulk Order

isotopic purity

≥97.0%

Quality Level

100

assay

≥97.0% (GC)

form

solid

reaction suitability

reaction type: C-C Bond Formation

functional group

acyl chloride

SMILES string

CC1(c2ccccc2-c3ccccc13)[13C](Cl)=O

InChI

1S/C15H11ClO/c1-15(14(16)17)12-8-4-2-6-10(12)11-7-3-5-9-13(11)15/h2-9H,1H3/i14+1

InChI key

ZQYOOHGEBHBNTP-UJKGMGNHSA-N

Application

COGen is a simple alternative for carbon monoxide generation in the application of palladium-catalyzed carbonylation reactions. This reagent has proved to be applicable in a wide range of applications and is compatible with several building blocks in the formation of ketones, amides, esters, etc.

For more information please visit: Technology Spotlight, Professor Skrystrup PPP

Use with the COware Platform

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Linkage

Frequently Asked Questions are available for this Product.

also commonly purchased with this product

Product No.
Description
Pricing

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
BCCH5498
BCCG9089
BCCG1189
BCCG4169
BCCF0920

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Palladium-catalyzed carbonylative α-arylation for accessing 1,3-diketones.
Thomas M Gøgsig et al.
Angewandte Chemie (International ed. in English), 51(3), 798-801 (2011-12-06)
[14C]-Carbon Monoxide
Journal of Labelled Compounds & Radiopharmaceuticals, 55, 411-418 (2012)
Thomas M Gøgsig et al.
Organic letters, 14(10), 2536-2539 (2012-05-09)
The direct carbonylative palladium catalyzed synthesis of monoprotected 1,3-ketoaldehydes is reported starting from aryl iodides applying near stoichiometric amounts of carbon monoxide. Besides representing platforms for a variety of heterocyclic structures, these motives serve as viable precursors for the highly
Korsager, S.;
Angewandte Chemie (International Edition in English) (2013)
Mia N Burhardt et al.
The Journal of organic chemistry, 77(12), 5357-5363 (2012-05-23)
We have synthesized two isotopically labeled variants of the β-amyloid binding compound FSB possessing (13)C-labels on the two terminal aryl carboxylic acid moieties. One of these was also fully deuterated on the olefinic spacers. The (13)C-isotope labeling was achieved applying
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