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742619

Sigma-Aldrich

tert-Amyl methyl ether

produced by INEOS Oligomers, ≥99.0% (GC)

Synonym(s):

METHOXYPENTANE™, 1,1-Dimethylpropyl methyl ether, Methyl 2-methyl-2-butyl ether, Methyl tert-pentyl ether, TAME

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About This Item

Linear Formula:
C2H5C(CH3)2OCH3
CAS Number:
994-05-8
Molecular Weight:
102.17
Beilstein/REAXYS Number:
1731452
EC Number:
213-611-4
MDL number:
MFCD00010186
UNSPSC Code:
12352100
PubChem Substance ID:
329765584

assay

≥99.0% (GC)

form

liquid

impurities

≤0.01% benzene
≤0.02% water
≤0.50% sum of C5-hydrocarbons
≤0.50% sum of C7-ethers
≤0.60% tert-amyl alcohol

refractive index

n20/D 1.389 (lit.)
n20/D 1.3896

bp

85-86 °C (lit.)

density

0.76-0.78 g/mL at 25 °C (lit.)

functional group

ether

SMILES string

CCC(C)(C)OC

InChI

1S/C6H14O/c1-5-6(2,3)7-4/h5H2,1-4H3

Inchi Key

HVZJRWJGKQPSFL-UHFFFAOYSA-N

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Application


  • Identification of environmental hazards of gasoline oxygenate tert-amyl methyl ether (TAME).: This study evaluates the environmental risks associated with the use of tert-Amyl methyl ether (TAME) as a gasoline oxygenate. The research highlights potential hazards to environmental and human health, underscoring the need for careful assessment and regulation of TAME use in fuels. (Huttunen et al., 1997).

Legal Information

METHOXYPENTANE is a trademark of INEOS Oligomers

Pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

19.4 °F - closed cup

flash_point_c

-7 °C - closed cup

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Certificates of Analysis (COA)

Lot/Batch Number
BCCK5624
BCCF4077
BCCC6331
BCBS3844V
BCBS1951V

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Sinikka Vainiotalo et al.
Journal of occupational health, 48(5), 347-357 (2006-10-21)
The exposure of gasoline pump repairers and inspectors to gasoline was studied at service stations and repair shops in Finland in April-June 2004. The average air temperature ranged from 7 degrees C to 16 degrees C and wind speed from
Dorothea M Kujawinski et al.
Journal of environmental monitoring : JEM, 12(1), 347-354 (2010-01-19)
In order to monitor the behaviour of contaminants in the aqueous environment effective enrichment techniques often have to be employed due to their low concentrations. In this work a robust and sensitive purge and trap-gas chromatography-isotope ratio mass spectrometry method
Maria Aivalioti et al.
Journal of hazardous materials, 207-208, 136-146 (2011-05-17)
The removal of BTEX (benzene, toluene, ethyl-benzene and m-,p-,o-xylenes), MTBE (methyl tertiary butyl ether) and TAME (tertiary amyl methyl ether) from aqueous solutions by raw (L(raw)) and thermally treated lignite at 250 C, 550 °C and 750 °C (L250, L550
Susan C J Sumner et al.
Journal of applied toxicology : JAT, 23(6), 419-425 (2003-11-25)
Interest in understanding the biological behavior of aliphatic ethers has increased owing to their use as gasoline additives. The purpose of this study was to investigate the blood pharmacokinetics of the oxygenate tertiary amyl methyl ether (TAME), its major metabolite
Janet M Benson et al.
Journal of toxicology and environmental health. Part A, 74(10), 638-657 (2011-03-25)
Chronic inhalation studies were conducted to compare the toxicity and potential carcinogenicity of evaporative emissions from unleaded gasoline (GVC) and gasoline containing the oxygenate methyl tertiary-butyl ether (MTBE; GMVC). The test materials were manufactured to mimic vapors people would be
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