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741701

Sigma-Aldrich

Ethyl 2-methyl-2-(phenylthiocarbonylthio)propionate

95%

Synonym(s):

2-(Ethoxycarbonyl)-2-propyldithiobenzoate, ECPDB

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About This Item

Empirical Formula (Hill Notation):
C13H16O2S2
CAS Number:
Molecular Weight:
268.39
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

assay

95%

form

liquid

refractive index

n20/D 1.600

density

1.148 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CCOC(=O)C(C)(C)SC(=S)c1ccccc1

InChI

1S/C13H16O2S2/c1-4-15-12(14)13(2,3)17-11(16)10-8-6-5-7-9-10/h5-9H,4H2,1-3H3

InChI key

MDFLMFRGXQRZII-UHFFFAOYSA-N

Application

RAFT agent for controlled radical polymerization; well-suited for polymerization of methacrylates, methacrylamides, and to a lesser extent styrenes, acrylates, and acrylamides. Chain Transfer Agent (CTA)

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Skin Sens. 1

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Articles

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

Protocols

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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