714836
Iodine monochloride solution
1 M in acetic acid
Synonym(s):
Chloroiodide solution, Wijs solution
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About This Item
Linear Formula:
ICl
CAS Number:
Molecular Weight:
162.36
Beilstein/REAXYS Number:
3587194
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22
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form
solution
concentration
1 M in acetic acid
density
1.143 g/mL at 25 °C
SMILES string
ClI
InChI
1S/ClI/c1-2
InChI key
QZRGKCOWNLSUDK-UHFFFAOYSA-N
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General description
Iodine monochloride is an inorganic reagent used in the iodination and chloroiodination of aromatic and unsaturated compounds, respectively. It is also used to cleave carbon-metal bonds.
Application
Iodine monochloride can be used:
- As a reagent in the preparation of α-iodo β-ketosulfones from β-ketosulfones.
- In the synthesis of 3-(4-bromo-2-methylphenyl)-4-iodosydnone, which is further used to prepare substituted pyrazoles.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B
Storage Class
3 - Flammable liquids
wgk_germany
WGK 3
flash_point_f
105.1 °F
flash_point_c
40.6 °C
Certificates of Analysis (COA)
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Synthesis of α-iodo β-ketosulfones and α-iodo methylsulfones using iodine monochloride
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Tetrahedron Letters, 47(26), 4319-4323 (2006)
Iodine monochloride
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Dumitracscu F, et al.
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Ru-Jin Huang et al.
Analytical chemistry, 81(5), 1777-1783 (2009-02-10)
This study concerns the development of a coupled diffusion denuder system capable of separating and quantifying gaseous molecular iodine (I(2)) and two other highly reactive iodine species, ICl and HOI, which are collectively named activated iodine compounds (AIC). Both I(2)
Zan Qu et al.
Journal of hazardous materials, 183(1-3), 132-137 (2010-08-03)
The removal of Hg(0) by the homogenous gas-phase reaction and particle-induced reaction was investigated under various conditions. Iodine monochloride was found to be efficient for Hg(0) oxidation, with the apparent 2nd-order rate constant of about 10.5(±0.3)×10(-17) cm(3) molecules(-1) s(-1) and
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