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708763

Sigma-Aldrich

[(S)-(−)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride

Synonym(s):

[PdCl2{(S)-4-tolylbinap}]

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About This Item

Empirical Formula (Hill Notation):
C48H40Cl2P2Pd
CAS Number:
215597-19-6
Molecular Weight:
856.10
MDL number:
MFCD11656205
UNSPSC Code:
12352005
PubChem Substance ID:
329762823

form

solid

mp

>300 °C

functional group

phosphine

SMILES string

Cl[Pd]Cl.Cc1ccc(cc1)P(c2ccc(C)cc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccc(C)cc7)c8ccc(C)cc8

InChI

1S/C48H40P2.2ClH.Pd/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;;;/h5-32H,1-4H3;2*1H;/q;;;+2/p-2

InChI key

ADMKISPNGKUJAU-UHFFFAOYSA-L

Application

Catalyst for:
  • Stereoselective preparation of hydroxymethyldihydronaphthalenone via alkylative ring opening of oxabenzonorbornadiene with (PhMe2SiCH2)2Zn followed by hydrogenation and Tamao-Fleming oxidation
  • Asymmetric synthesis of cyclopentylindanes via cyclization of bromo- and trifluoromethanesulfonyloxyphenylheptenylmalonate

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
14496CK

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