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704091

Sigma-Aldrich

Tributyltin hydride solution

1 M in cyclohexane

Synonym(s):

Tributylstannane, Tributylstannyl hydride

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About This Item

Empirical Formula (Hill Notation):
C12H28Sn
CAS Number:
Molecular Weight:
291.06
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

form

liquid

reaction suitability

reagent type: reductant

concentration

1 M in cyclohexane

refractive index

n20/D 1.438

density

0.895 g/mL at 25 °C

SMILES string

CCCC[SnH](CCCC)CCCC

InChI

1S/3C4H9.Sn.H/c3*1-3-4-2;;/h3*1,3-4H2,2H3;;

Inchi Key

DBGVGMSCBYYSLD-UHFFFAOYSA-N

Application

Reactant or reagent for:
  • Alkyne hydrostannations
  • Intramolcular cyclization for the synthesis of zoanthamine alkaloids
  • Stereoselective C-glycosylation of pyranosides using Heck allylation
  • Synthesis of phenylbutenoid dimers for use in treating diseases
  • Preparation of N-acyl derivatives of ecteinascidin 770
  • Syntehsis of cyclonucleosides using black light induced radical cyclization

flash_point_f

5.0 °F

flash_point_c

-15 °C


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Cassander P Titley-O'Neal et al.
The Science of the total environment, 449, 52-62 (2013-02-16)
Queen conch (Strombus gigas) are listed in CITES Appendix II. Populations may be declining due to anthropogenic inputs that include pollutants from boating activity. In the British Virgin Islands (BVI), some conch exhibit imposex, a condition in which male external
Shanshan Zhu et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 921-922, 21-26 (2013-02-19)
Analysis of tributyltin chloride (TBT) in environmental samples, such as seawater, is important in order to evaluate the TBT contamination and accumulation in the trophic chain. The environmental impact of organotin compounds has been a particular focus of analytical studies.
Detection, monitoring, and control of tributyltin--an almost complete success story.
Peter Matthiessen
Environmental toxicology and chemistry, 32(3), 487-489 (2013-02-19)
Robert W Chapman et al.
Molecular ecology, 22(6), 1485-1487 (2013-04-20)
Reproduction is the goal of living organisms, and environmental conditions that influence sexual development are therefore critical to understanding adaptation in natural populations. It is not surprising that so much attention has been devoted to the impacts of the physical
Ang Yu et al.
Aquatic toxicology (Amsterdam, Netherlands), 128-129, 158-162 (2013-01-15)
Tributyltin (TBT) is a ubiquitous marine contaminant due to its extensive use as a biocide, fungicide and antifouling agent. However, the neurotoxic effect of TBT has not been extensively studied, especially in marine fish. This study was conducted to investigate

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