702730
tert-Butylchlorodiphenylsilane solution
1 M in methylene chloride
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About This Item
Empirical Formula (Hill Notation):
C16H19ClSi
CAS Number:
Molecular Weight:
274.86
MDL number:
UNSPSC Code:
12352002
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
form
liquid
Quality Level
concentration
1 M in methylene chloride
bp
40 °C
density
1.249 g/mL at 25 °C
SMILES string
CC(C)(C)[Si](Cl)(c1ccccc1)c2ccccc2
InChI
1S/C16H19ClSi/c1-16(2,3)18(17,14-10-6-4-7-11-14)15-12-8-5-9-13-15/h4-13H,1-3H3
InChI key
MHYGQXWCZAYSLJ-UHFFFAOYSA-N
Application
tert-Butylchlorodiphenylsilane can be used to prepare 1-benzyloxy-3-(tert-butyldiphenylsilyloxy)propan-2-ol, a key intermediate for the synthesis of mono-O-protected pyrimidine acyclic nucleosides.
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system, Respiratory system
Storage Class
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles
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A new synthetic route towards the mono-O-protected anti-conformationally constrained pyrimidine acyclic nucleoside
Liu C, et al.
Chemical & Pharmaceutical Bulletin, 50(8), 1028-1030 (2002)
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