Skip to Content
MilliporeSigma
All Photos(1)

Documents

701785

Sigma-Aldrich

Bis(trifluoroacetato)carbonylbis(triphenylphosphine)ruthenium(II) methanol adduct

Synonym(s):

Carbonylbis(trifluoroacetato)bis(triphenylphosphine)ruthenium

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C41H30F6O5P2Ru
Molecular Weight:
879.68
MDL number:
MFCD06658132
UNSPSC Code:
12161600
PubChem Substance ID:
329762320
NACRES:
NA.22

form

solid

reaction suitability

core: ruthenium
reagent type: catalyst

mp

236-237 °C

SMILES string

CO.[C-]#[O+].FC(F)(F)C(=O)O[Ru]OC(=O)C(F)(F)F.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6

InChI

1S/2C18H15P.2C2HF3O2.CH4O.CO.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2*3-2(4,5)1(6)7;2*1-2;/h2*1-15H;2*(H,6,7);2H,1H3;;/q;;;;;;+2/p-2

InChI key

GQNGUAPNKNMOTM-UHFFFAOYSA-L

Related Categories

Application

Catalyst used in the hydroacylation of 2-butyne.
Vinylation of alcohols or aldehydes.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Vanessa M Williams et al.
Tetrahedron, 65(26), 5024-5029 (2010-07-09)
Under the conditions of ruthenium catalyzed transfer hydrogenation, 2-butyne couples to alcohols 1a-1j to deliver alpha,beta-unsaturated ketones 3a-3j in good to excellent isolated yields with complete E-stereoselectivity. Under identical conditions, aldehydes 2a-2j couple to 2-butyne to provide an identical set
Ryan L Patman et al.
Journal of the American Chemical Society, 131(6), 2066-2067 (2009-01-29)
Under the conditions of ruthenium catalyzed transfer hydrogenation, 2-butyne couples to benzylic and aliphatic alcohols 1a-1l to furnish allylic alcohols 2a-2l, constituting a direct C-H vinylation of alcohols employing alkynes as vinyl donors. Under related transfer hydrogenation conditions employing formic

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service