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About This Item
Empirical Formula (Hill Notation):
C13H14BNO4
CAS Number:
Molecular Weight:
259.07
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
assay
95%
form
powder
mp
185-195 °C
SMILES string
CN1CC(=O)OB(OC(=O)C1)\C=C\c2ccccc2
InChI
1S/C13H14BNO4/c1-15-9-12(16)18-14(19-13(17)10-15)8-7-11-5-3-2-4-6-11/h2-8H,9-10H2,1H3/b8-7+
InChI key
OFLDLTAQNBBGGU-BQYQJAHWSA-N
Application
trans-2-Phenylvinylboronic acid MIDA ester is a stable boronic acid surrogate, which can be used as a reactant in Suzuki-Miyaura cross-coupling reactions . It is also used as a precursor to prepare α-borylated phenyl ketone via the Wacker-type oxidation method.
Storage Class
13 - Non Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Synthesis of ?-borylated ketones by regioselective wacker oxidation of alkenylboronates
Corless VB, et al.
Organic Letters, 20(17), 5300-5303 (2018)
Nicholas A Isley et al.
Journal of the American Chemical Society, 135(47), 17707-17710 (2013-11-15)
New technology has been developed that enables Suzuki-Miyaura couplings involving widely utilized MIDA boronates to be run in water as the only medium, mainly at room temperature. The protocol is such that no organic solvent is involved at any stage;
Panchanan Maiti et al.
International journal of molecular sciences, 21(18) (2020-09-17)
Alzheimer's disease (AD) is characterized by amyloid (Aβ) aggregation, hyperphosphorylated tau, neuroinflammation, and severe memory deficits. Reports that certain boronic compounds can reduce amyloid accumulation and neuroinflammation prompted us to compare trans-2-phenyl-vinyl-boronic-acid-MIDA-ester (TPVA) and trans-beta-styryl-boronic-acid (TBSA) as treatments of deficits
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