698555

1,1′-Bis(dichlorophosphino)ferrocene

≥96%

• Empirical Formula (Hill Notation): C₁₀H₈Cl₄FeP₂
• CAS Number: 142691-70-1
• Molecular Weight: 387.78
• MDL number: MFCD01630854
• UNSPSC Code: 12352101
• PubChem Substance ID: 329762010

Properties

• assay: ≥96%
• form: powder
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• mp: 67-71 °C
• functional group: phosphine
• SMILES string: [Fe].ClP(Cl)[C]1[CH][CH][CH][CH]1.ClP(Cl)[C]2[CH][CH][CH][CH]2
• InChI: 1S/2C5H4Cl2P.Fe/c2*6-8(7)5-3-1-2-4-5;/h2*1-4H;
• InChI key: CSJDQGIPHURAPH-UHFFFAOYSA-N

Description

Application

Reactant for synthesis of:

• Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation
• Metallocene-bridged bisphosphaalkene

Catalyst for synthesis of oligonuclear heterometallic complexes

Safety Information

• pictograms: GHS05
• signalword: Danger
• hcodes: H314
• pcodes: P280 - P305 + P351 + P338 - P310
• Hazard Classifications: Skin Corr. 1B
• Storage Class: 8B - Non-combustible corrosive hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges