Skip to Content
MilliporeSigma
All Photos(2)

Documents

682071

Sigma-Aldrich

2-(Hydroxymethyl)phenylboronic acid cyclic monoester

97%

Synonym(s):

1,3-Dihydro-1-hydroxy-2,1-benzoxaborole, 2-(Hydroxymethyl)phenylboronic acid hemiester

Sign Into View Organizational & Contract Pricing


About This Item

Empirical Formula (Hill Notation):
C7H7BO2
CAS Number:
Molecular Weight:
133.94
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

assay

97%

form

solid

mp

95-100 °C

SMILES string

OB1OCc2ccccc12

InChI

1S/C7H7BO2/c9-8-7-4-2-1-3-6(7)5-10-8/h1-4,9H,5H2

InChI key

XOQABDOICLHPIS-UHFFFAOYSA-N

Application

Oxaboroles and benzoxaboroles are useful substrates to prepare allylic and benzylic alcohols via Suzuki coupling.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Synthesis, 1148-1148 (2006)
Eric C Hansen et al.
Journal of the American Chemical Society, 128(25), 8142-8143 (2006-06-22)
A novel mode of regiochemical control over the allylic [1,3]-transposition of silyloxy groups catalyzed by Re2O7 has been developed. This strategy relies on a cis-oriented vinyl boronate, generated from the Alder-ene reaction of homoallylic silyl ethers and alkynyl boronates, to

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service