676187

Di-tert-butylneopentylphosphine

95%

• Synonym(s): Bis(1,1-dimethylethyl)(2,2-dimethylpropyl)phosphine
• Empirical Formula (Hill Notation): C₁₃H₂₉P
• CAS Number: 60633-21-8
• Molecular Weight: 216.34
• MDL number: MFCD09038438
• UNSPSC Code: 12352001
• PubChem Substance ID: 24884840
• NACRES: NA.22

Properties

• assay: 95%
• form: solid
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Cross Couplings
• refractive index: n20/D 1.478
• bp: 40 °C/0.1 mmHg
• density: 0.839 g/mL at 25 °C
• functional group: phosphine
• storage temp.: −20°C
• SMILES string: CC(C)(C)CP(C(C)(C)C)C(C)(C)C
• InChI: 1S/C13H29P/c1-11(2,3)10-14(12(4,5)6)13(7,8)9/h10H2,1-9H3
• InChI key: JBGICSFDKZAWFJ-UHFFFAOYSA-N

Description

Application

Reactant for:

• Highly active palladium complexes
• Synthesis of organometallic compounds of iridium and rhodium

Ligand for cross coupling of aryl bromides and chlorides

Safety Information

• pictograms: GHS02,GHS05,GHS07
• signalword: Danger
• hcodes: H250,H302,H312,H314
• pcodes: P222 - P231 - P280 - P305 + P351 + P338 - P310 - P422
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Pyr. Sol. 1 - Skin Corr. 1B
• Storage Class: 4.2 - Pyrophoric and self-heating hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges