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672777

Sigma-Aldrich

(+)-1-Benzyl-[(3R,4R)-bis(diphenylphosphino)]pyrrolidine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

98%

Synonym(s):

(3R-trans)-3,4-Bis(diphenylphosphino)-1-(phenylmethyl)pyrrolidine rhodium complex, catASium® D(R)Rh

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About This Item

Empirical Formula (Hill Notation):
C43H45BF4NP2Rh
CAS Number:
Molecular Weight:
827.48
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:

assay

≥98% (31P-NMR)
98%

SMILES string

[F-].FB(F)F.C1CC=CCCC=C1.C[Rh+]2[PH]([C@@H]3CN(C[C@H]3[PH]2(c4ccccc4)c5ccccc5)Cc6ccccc6)(c7ccccc7)c8ccccc8

InChI

1S/C35H33NP2.C8H12.BF4.Rh/c1-6-16-29(17-7-1)26-36-27-34(37(30-18-8-2-9-19-30)31-20-10-3-11-21-31)35(28-36)38(32-22-12-4-13-23-32)33-24-14-5-15-25-33;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h1-25,34-35H,26-28H2;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t34-,35-;;;/m1.../s1

InChI key

HNTLYZLJAZBMKG-JMVIWXBZSA-N

General description

sold in collaboration with Solvias AG

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Legal Information

catASium is a registered trademark of Umicore AG & Co. KG

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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