669393
N-Methyl-O-benzoylhydroxylamine hydrochloride
97%
Synonym(s):
Benzoic acid N-hydroxymethylamine ester hydrochloride
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About This Item
Linear Formula:
(C6H5)CO2(NHCH3) HCl
CAS Number:
Molecular Weight:
187.62
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22
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assay
97%
form
solid
mp
133 °C (dec.)
functional group
amine
phenyl
storage temp.
2-8°C
SMILES string
[Cl-].C[NH2+]OC(=O)c1ccccc1
InChI
1S/C8H9NO2.ClH/c1-9-11-8(10)7-5-3-2-4-6-7;/h2-6,9H,1H3;1H
InChI key
FTCDQNQIGUCFSA-UHFFFAOYSA-N
Application
Benzoylation Reagents Simple Tools for a-Oxygenation of Aldehydes and Ketones
Reactant for preparation of:
Reactant for preparation of:
- NHC-catalyzed redox esterification and cycloaddition reactions
- Pd/pyrrolidine-catalyzed Tsuji-Trost cyclization of aldehydes
- α-acyloxy ketones via oxyacylation reaction
Reagent for α-acyloxylation of aldehydes and ketones. The reagent is not sensitive to air and moisture.[1]
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Cory S Beshara et al.
Organic letters, 7(25), 5729-5732 (2005-12-03)
[chemical reaction: see text]. A simple, one-pot method for the alpha-acyloxylation of carbonyl compounds that proceeds at room temperature in the presence of both moisture and air has been developed. Treatment of a variety of aldehydes and both cyclic and
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