667226

Chlorohydridotris(triphenylphosphine) ruthenium(II) toluene adduct

• Linear Formula: HRuCl · 3(P(C₆H₅)₃) ·C₆H₅CH₃
• CAS Number: 217661-36-4
• Molecular Weight: 1016.53
• UNSPSC Code: 12161600
• PubChem Substance ID: 24884895

Properties

• form: solid
• reaction suitability: core: ruthenium; reagent type: catalyst
• storage temp.: 2-8°C
• SMILES string: Cl[RuH].Cc1ccccc1.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7.c8ccc(cc8)P(c9ccccc9)c%10ccccc%10
• InChI: 1S/3C18H15P.C7H8.ClH.Ru.H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;;/h3*1-15H;2-6H,1H3;1H;;/q;;;;;+1;/p-1
• InChI key: FPDVFAUPHLXLMN-UHFFFAOYSA-M

Description

Application

Reactant for synthesis of:

• Dithiolate-bridged ruthenium-rhodium heterobimetallic dihydride complex
• Amido / phosphine pincer hydrides of ruthenium

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H302 + H312 + H332,H315,H319,H335
• pcodes: P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves