665185

Bis(chlorogold(I)) bis(diphenylphosphino)methane

97%

• Synonym(s): Methylenebis[diphenyl]phosphine gold complex
• Empirical Formula (Hill Notation): C₂₅H₂₂Au₂Cl₂P₂
• CAS Number: 37095-27-5
• Molecular Weight: 849.23
• MDL number: MFCD08705280
• UNSPSC Code: 12161600
• PubChem Substance ID: 24884721
• NACRES: NA.22

Properties

• Quality Level: 100
• assay: 97%
• form: solid
• reaction suitability: core: gold; reagent type: catalyst
• SMILES string: Cl[Au][PH](C[PH]([Au]Cl)(c1ccccc1)c2ccccc2)(c3ccccc3)c4ccccc4
• InChI: 1S/C25H22P2.2Au.2ClH/c1-5-13-22(14-6-1)26(23-15-7-2-8-16-23)21-27(24-17-9-3-10-18-24)25-19-11-4-12-20-25;;;;/h1-20H,21H2;;;2*1H/q;2*+1;;/p-2
• InChI key: JNPUWTQJFLJEJC-UHFFFAOYSA-L

Description

Application

Gold Catalysts — 21st Century ′Gold Rush′

Used for

• Pharmacological studies involving the anticancer activity of gold(I)-phosphine complexes as autophagy-inducing agents
• Triplet luminescent light emitting diodes with low turn-on voltage

Catalyst for:

• Stereoselective preparation of vinyltetrahydrofuran via intramolecular hydroalkoxylation
• Hydroamination and hydroalkoxylation reactions
• Asymmetric transition metal catalysis
• Gold(I) catalyzed intramolecular Schmidt reactions of homopropargyl azides

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)