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Key Documents

660167

Sigma-Aldrich

Sodium silica gel Stage I

extent of labeling: ~35 wt. % Na-K loading

Synonym(s):

Na-SG-I

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About This Item

MDL number:
MFCD01941718
UNSPSC Code:
11101527
NACRES:
NA.22

form

solid

Quality Level

100

autoignition temp.

248-257 °F

reaction suitability

reagent type: reductant

extent of labeling

~35 wt. % Na-K loading

Application

Alkali Metal Silica Gels from SiGNa
Alternative to other reagents for desulfurizations, dehalogenations(as Wurtz coupling reactions), and Birch reductions.

Additionally can be used as:
  • A reducing agent for aliphatic ester substrates
  • A deprotectant in place of the typical heavy metal deprotectant

pictograms

FlameCorrosion
GHS02,GHS05

signalword

Danger

hcodes

H261,H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - Water-react 2

supp_hazards

EUH014

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKCD7545
MKCD4917
MKCD9622
MKCF2199
MKBW6152V

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P. Nandi, et al.,
Tetrahedron Letters, 50, 3864-3866 (2009)
P. F. Vogt and B. Bodnar,
Spec. Chem., 29, 22-24 (2009)
Dye, J. L. et al
Journal of the American Chemical Society, 127, 9339-9339 (2005)

Articles

Alkali Metal Silica Gels from SiGNa

SiGNa Chemistry has recently developed a technology for encapsulating alkali metals into nano-structured porous oxides to create stable, free flowing powders with varying reactivities (based on the intended application).

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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