594334

Benzenecyclopentadienyliron(II) hexafluorophosphate

• Empirical Formula (Hill Notation): C₁₁H₁₁F₆FeP
• CAS Number: 12176-31-7
• Molecular Weight: 344.01
• MDL number: MFCD05664319
• UNSPSC Code: 12352300
• PubChem Substance ID: 24881498

Properties

• form: solid
• reaction suitability: reagent type: catalyst; core: iron
• mp: 268 °C (dec.) (lit.)
• SMILES string: [Fe+].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH][CH]2.F[P-](F)(F)(F)(F)F
• InChI: 1S/C6H6.C5H5.F6P.Fe/c1-2-4-6-5-3-1;1-2-4-5-3-1;1-7(2,3,4,5)6;/h1-6H;1-5H;;/q;;-1;+1
• InChI key: ZFDATMJBJWNTMT-UHFFFAOYSA-N

Description

Application

Catalyst for:

• Nitroxide-mediated photochemical-living radical polymerization reactions
• Assembly of complex photonic crystals
• Preparation of cyclopentadien-iron-biphenyl hexafluorophosphate ([Cp-Fe-biphenyl]+PF6-) for cationic photopolymerization of epoxy systems

Reactant for:

• LIgand exchange reactions
• Solid-state synthesis of carbon nanostructures

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves