548707

4-Methylbenzamide oxime

97%

• Synonym(s): p-Toluamideoxime
• Linear Formula: CH₃C₆H₄C(NH₂)=NOH
• CAS Number: 19227-13-5
• Molecular Weight: 150.18
• MDL number: MFCD00019952
• UNSPSC Code: 12352100
• PubChem Substance ID: 24879052
• NACRES: NA.22

Properties

• assay: 97%
• mp: 140-145 °C (lit.)
• SMILES string: Cc1ccc(cc1)\C(N)=N/O
• InChI: 1S/C8H10N2O/c1-6-2-4-7(5-3-6)8(9)10-11/h2-5,11H,1H3,(H2,9,10)
• InChI key: NKJXMLIWSJATEE-UHFFFAOYSA-N

Description

General description

4-Methylbenzamide oxime is a benzonitrile derivative that can be prepared from 4-methylbenzonitrile and hydroxylamine hydrochloride. Its crystalline structure shows the presence of both intramolecular and intermolecular hydrogen bonds. 3-Aryl-5-trinitromethyl-1,2,4-oxadiazoles undergoes hydrolysis under acidic conditions to form 4-methylbenzamide oxime as one of the product.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves