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498823

Sigma-Aldrich

2-Methoxyphenylzinc iodide solution

0.5 M in THF

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About This Item

Linear Formula:
CH3OC6H4ZnI
CAS Number:
Molecular Weight:
299.42
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

concentration

0.5 M in THF

density

0.996 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

COc1ccccc1[Zn]I

InChI

1S/C7H7O.HI.Zn/c1-8-7-5-3-2-4-6-7;;/h2-5H,1H3;1H;/q;;+1/p-1

InChI key

ODPBGCGZGQFTSZ-UHFFFAOYSA-M

Application

2-Methoxyphenylzinc iodide can be used:
  • As a substrate in the synthesis of aryl ketones by reacting with aroyl chlorides.[1]
  • As a starting material in the synthesis of sulfones by reacting with DABSO reagent and alkyl halides.[2]

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

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Danger

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system, Respiratory system

supp_hazards

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

1.4 °F - closed cup

flash_point_c

-17 °C - closed cup


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A versatile protocol for the preparation of highly hindered aryl ketones using organozinc reagents
Cho H and Kim S
Bulletin of the Korean Chemical Society,, 33(9), 3083-3086 (2012)
Synthesis of sulfones from organozinc reagents, DABSO, and alkyl halides
Rocke BN, et al.
Organic Letters, 16(1), 154-157 (2014)

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