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Key Documents

446378

Sigma-Aldrich

tert-Butyl(4-chlorobutoxy)dimethylsilane

98%

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About This Item

Linear Formula:
Cl(CH2)4OSi(CH3)2C(CH3)3
CAS Number:
Molecular Weight:
222.83
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

assay

98%

form

liquid

refractive index

n20/D 1.439 (lit.)

bp

201 °C (lit.)

density

0.87 g/mL at 25 °C (lit.)

functional group

chloro

SMILES string

CC(C)(C)[Si](C)(C)OCCCCCl

InChI

1S/C10H23ClOSi/c1-10(2,3)13(4,5)12-9-7-6-8-11/h6-9H2,1-5H3

InChI key

MTQPZXNVDIKRAK-UHFFFAOYSA-N

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

179.6 °F - closed cup

flash_point_c

82 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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Gary A Molander et al.
The Journal of organic chemistry, 67(11), 3861-3865 (2002-05-25)
Samarium(II) iodide, in the presence of catalytic amounts of nickel(II) iodide, has been used to promote intramolecular conjugate additions of alkyl halides onto alpha,beta-unsaturated lactones. This process has been shown to be applicable to a number of alpha,beta-unsaturated lactones, including

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